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In humans, this enzyme family serves as one of the critical antioxidant mechanisms, readily scavenging reactive oxides and peroxides that are naturally or exogenously produced, protecting cells and structures from oxidative damage 31

In a hypoxic and glucose-deprived TME, The metabolism of Gln is essential for tumor cells to survive and multiply ( Additionally, metabolomic analyses reveal low levels of Gln and elevated levels of glutamate in TNBC, suggesting that TNBC is more dependent on Gln and more sensitive to therapies targeting Gln breakdown compared to other breast cancer subtypes ( The role of Gln is critical in both the proliferation and metastasis of cancer cells

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